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99 Cards in this Set
- Front
- Back
How does primary (transient) creep change?
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Creep rate decreases.
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How does secondary creep change?
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The creep rate is constant.
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How does tertiary creep change?
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The creep rate increases.
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What are the x and y axes of a graph of the mechanical or failure characteristics of metals?
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Time and strain, respectively.
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What are the consequences of either increasing stress or temperature?
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The rupture lifetime diminishes, and the steady creep rate increases.
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Above about what temperature does creep become an important failure mechanism for a metal?
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at 40% of the melting point of the material, T_m
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What four metallurgical/processing techniques are employed to enhance the creep resistance of metal alloys?
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unidirectional solidification of allows, increasing the grain size or producing a grain structure with a preferred orientation, dispersion strengthening by using an insoluble second phase and solid solution alloying
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The heating of a homogenous and isotropic rod of solid material for which axial motion is restrained, results in which type of thermal stresses?
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compressive
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What conditions must an alloy meet to have complete solid solubility?
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similar atom size, similar electonegativities, same valence, same structure for A and B and A and B don't form intermediate chemical compounds
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What is the solidus line in a phase diagram?
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The border between which an alloy switches between a solid and a solid-liquid solution.
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What is the solvus in a phase diagram?
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This border, from which an alloy switches between a mixed phase solution and single phase solution, denotes the solubility limit.
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What is a eutectic structure?
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This microconstituent, that is not a phase, is stable at room temperature because diffusion is very slow.
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What is precipitation hardening (strength hardening, age hardening?)
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This process creates a dense and fine dispersion of precipitated particles in a matrix of deformable metal.
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What are precipitated particles?
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These particles act as obstacles to dislocation motion.
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What is a non-equilibrium structure?
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The structure of an alloy consists of supersaturated solid solution.
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What is a quenching medium?
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Water or oil is typically the medium that is used to rapidly cool material to a lower temperature in the process of precipitation hardening.
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What is a supersaturated solid solution?
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This solid solution has a phase in which there is the same amount of metal B as in the overall composition rather than the equilibrium amount.
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What is natural aging?
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This process uses room temperature.
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What is artificial aging?
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This process uses a temperature that is usually 15-25% of the difference between room and solutionizing temperature.
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What is aging?
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This process is necessary to finely disperse precipitate forms that lower the energy state of the material.
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What is the principle difference between wrought and cast alloys?
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Wrought alloys are ductile enough so as to be hot or cold worked during fabrication, where as cast alloys are brittle to the degree that shaping by deformation is not possible and they must be fabricated by casting.
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What is gray cast iron?
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This metal or alloy is most suitable for for milling machine base.
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What is stainless steel?
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This metal or alloy is most suitable for walls of a steam boiler. It has excellent corrosion resistance and contains more than 11%wt Cr.
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What is titanium alloy?
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This metal or alloy is most suitable for high speed aircraft.
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What is tool steel?
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This metal or alloy is most suitable for a drill bit.
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What is aluminum?
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This metal or alloy is most suitable for a cryogenic (very low temperature) container.
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What is magnesium?
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This metal or alloy is most suitable for pyrotechnics (i.e. fireworks or flares.)
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What is platinum?
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This metal or alloy is most suitable for high temperature furnace elements to be used in oxidizing environments.
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What are the primary constituents of brass?
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Copper and Zinc
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Which type of nonferrous alloy is amenable to mechanical deformation?
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wrought
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What are desirable characteristics of the noble metals?
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high electrical conductivities, oxidation resistance and high ductilities
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What are mechanical properties characteristic of the refractory metals?
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high strengths and high melting temperatures
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What are Molybdenum, Tungsten, Tantalum and Niobium?
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These metals are refractory metals.
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What are Iron, Nickel and Cobalt?
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These metals are the primary superalloy metals.
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What is yield strength?
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The magnitude of the applied stress must at least exceed this strength during metal forming operations.
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increases hardenability
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How does increasing carbon content influence the hardenability of a steel?
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What is hardenability?
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This characteristic is a material's ability to form martensite throughout the entirety of a piece.
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true
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For crystalline ceramics, plastic deformation occurs by the motion of dislocations. (T/F)
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What are Tungsten carbide, Aluminum oxide, Silica sand, Silicon carbide and Diamond?
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These materials are used as abrasive ceramics.
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What are high temperature stability, high toughness, and high wear resistance?
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These properties are required for abrasive ceramics.
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What are iron and its alloys?
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These metals account for 90% of the world's production of metals.
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What is an iron-carbide system?
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This system has the combined benefits of good strength, toughness and ductility at relatively low cost.
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What is the reason for the common use of the Fe-Fe3C phase diagram?
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High carbon content alloys are not useful for most applications.
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What is ferrite?
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This alpha phase is an interstitial solid solution of carbon in BCC iron ((delta r)/r is large,) its maxium solubility of carbon in BCC iron is 0.022 weight percent carbon at 727 degrees Celsius and .008 percent weight carbon at room temperature, and this material is soft and ductile.
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What is austentite?
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This gamma phase is an interstitial solid solution of carbon in FCC iron, and its maximum solubility of carbon in FCC iron is 2.14% weight carbon at 1147 degrees Celsius and .76% weight carbon at 727 degrees Celsius.
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What is cementite (Fe3C?)
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This metastable phase (not equilibrium phase on phase diagram but stable at room temperature) is a stoichiometric , intermetallic, hard and brittle compound with a composition of 6.7% weight carbon and 93.3% wt iron.
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What is wrought iron?
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This soft and easy to form alloy has less than. 008% weight carbon and is used for pipes, certain gates and nails.
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What are steels?
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This alloy has between .008% and 2.14% weight carbon (in practice, typically less than 1%.)
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What is cast iron?
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This hard, brittle alloy fabricated by melting and casting with 2.14% to 6.7% weight carbon is used for engine blocks, high temperature gears and valves (applications depend on additional alloying elements.)
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What is the eutectoid reaction in an iron carbide system?
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This reaction occurs at 727 degrees Celsius with .76% weight Carbon.
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What is pearlite?
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This eutectoid microconstituent composed of cementite and ferrite is a lamellar structure that looks like mother of pearl under a microscope and has properties that lie between those of soft, ductile ferrite and hard, brittle cementite. It also needs carbon diffusion to occur, and its transformation is dependent on time and temperature.
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What is a hypoeutectoid?
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This structure has a carbon content between .22% and .76% which is less than that of the eutectoid.
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What is a hypereutectoid?
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This structure has a carbon content between .76% and 2.14% which is more than that of the eutectoid.
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What are austentite stabilizers?
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These elements - Mn, Ni, Co, N, Cu, Zn - lower the eutectoid temperature.
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What are ferrite stabilizers?
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These elements - Si, Cr, Mo, W, V, Ti, Al - raise the eutectoid temperature.
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What are reasons for alloys?
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These reasons are solid solution strengthening, increasing corrosion resistance and forming carbides (high hardness and T strength.)
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What is heat treatment of steels?
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This process can create different mechanical properties by varying heating/cooling temperatures.
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What is coarse pearlite?
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This eutectoid microconstituent is formed by rapidly cooling steel to just below the eutectoid temperature and holding it there. It has thick lamellar layers (fast diffusion of carbon.)
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What is fine pearlite?
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This eutectoid microconstituent is formed by rapidly cooling steel below the eutectoid temperature and holding it there. It has thin lamellar layers (slow diffusion of carbon.) It is stronger, harder and less ductile than its other form because it has more phase boundaries to impede dislocation motion.) It is also harder and stronger than austentite.
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What is bainite?
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This microconstituent forms at temperatures below the temperature for pearlite formation and forms needles or plates.
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What is speroidite?
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This microconstituent forms if alloy with pearlite or bainite structure is heated to just below eutectoid temperature and held for a long time.
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What is martensite?
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This microconstituent forms if steel is cooled rapidly enough (quenched) to prevent carbon diffusion. Its transformation is only dependent on temperature (independent of time) -> athermal transformation. It has a plate-like or needle-like appearance and a body centered tetragonal (BCT) structure. It is the hardest and strongest of all microconstituents. Its ductility is negligible (very brittle.) Its properties are related to interstitial carbon atoms hindering dislocation movement (solid solution strengthening) and the few slips systems in its BCT structure.
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What is tempered martensite?
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This microconstituent enhances ductility and toughness by relieving internal stresses in material without compromising much strength. It must be held at an elevated temperature and forms alpha structures with very fine particles of ferrite (reverts to BCC structure.) Tempering it for a very long time eventually leads to spheroidite.
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What are plain carbon steels?
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These materials contain carbon and .3 -.95%wt Mn (only residual concentrations of other impurities.)
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What are low carbons steels?
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These materials contain less than .25%wt carbon and are soft and weak with good ductility and toughness. Their strengthening is achieved by cold working (can't form martensite.) They are the least expensive of their class to produce and used for fenders, nails, wires and pipes.
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What are medium carbon steels?
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These materials contain .25-.6%wt carbon and are stronger than its lower carbon class. It has low ductility, toughness and hardenability and is used for gears, axles, bolts and shafts.
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What are high carbon steels?
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These materials contain between .6-1.4%wt carbon, are the hardest, strongest and least ductile of their class and use and used for knives, saw blades, chisels and hammers.
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What are alloy steels?
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These materials are created by adding elements to improve properties of their plain carbon class.
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What are high strength, low allow steels?
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These materials have less than 10%wt alloying additions. They have Cu, V, Ni and Mo added to their low carbon class to increase strength and corrosion resistance.
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What are heat treatable steels?
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These materials have Cr, Ni and Mo added to their medium carbon class to increase hardenability.
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What are tool and die steels?
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These materials have Cr, V, W and Mo added to their high carbon class to form very hard and wear-resistant carbides.
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What is ferritic stainless steel?
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This material contains very little carbon and 12-30%wt Cr, is strengthened by cold working and used for high temperature valves, combustion chambers and range hoods.
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What is austentitic stainless steel?
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This materials contains very little carbon, 16-25%wt Cr and 7-20%wt Ni, is strengthened by cold working, has the highest corrosion resistance of its class and is used for signs, wires and food processing equipment.
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What is martensitic stainless steel?
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This material contains .15-1%wt carbon and 12-17%wt Cr, is quenched to form martensite, has a composition chosen to optimize strength and hardness (has lowest corrosion resistance of its class) and is used for cutlery, bearings and surgical tools.
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What are ceramic materials?
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These materials are inorganic, non-metallic, (include glass) and consist of metallic ???
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What are tradition ceramics?
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These materials are made from clay, silica and feldspar and used for bricks, tiles and electrical porcelain.
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What are engineering ceramics?
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These materials are pure or nearly pure compounds (oxides, carbides and nitrides) and used for structural, optical, electrical and biological applications.
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What is an amorphous ceramic structure?
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Glass has this structure.
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What is a crystalline ceramic structure?
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This structure is determined by the size of ions (cation and anions) and magnitude of electrical charge on the ions (must maintain charge neutrality.)
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What is a rock-salt structure?
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This AX structure (AX structure: A=cation X=anion) has two interpenetrating FCC lattices and a coordination number of six for both cations and anions. NaCl, MgO, LiF and FeO have this structure.
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What is a cesium chloride structure?
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This AX structure is simple cubic (not BCC because ions are different types and has a coordination number of eight for both anions and cations. CsCl, CsBr, TiCl and TiBr have this structure.
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What is a zinc blende structure?
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This AX structure has anions that form the FCC structure and cations that occupy half of tetrahedral sites. Its coordination number is for both cations and anions is four. It is covalently bonded. ZnS, SiC, GaAs and CdS (many semiconductors) have this structure.
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What is a perovskite structure?
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This ABX3 structure has cations A with a coordination of 12, cations B with a coordination number of 6 and anions with a coordination number of 6. CaTiO3, BaTiO3, SrTiO3, CaZrO3 and LaAlO3 have this structure.
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What is a Frenkel point defect?
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This defect is when a cation moves to an interstitial site while still maintaining charge neutrality.
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What is Schottky point defect?
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This defect occurs when a missing cation and anion are missing.
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What is a flexural test?
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This method is used to determine the strength of ceramics. There are two types the three point and the four point. It is used more commonly than the tensile test with ceramics because it is difficult to make and handle ceramic tensile specimens.
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What is dislocation motion?
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This mechanism of plastic deformation is the same in ceramics as in metals.
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What are the reasons the small plastic deformation in ceramics?
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There are few slip systems (slip planes and slip directions) and low dislocation densities because of the charge neutrality requirement.
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What is a brittle fracture?
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This fracture allows little plastic deformation because the fracture strength depends on the flaw size.
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What are ways to increase fracture strength?
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Using the material in compression does not allow cracks to grow. The flaw size can be decreased by using fibers rather than bulk ceramic (smaller flaws in fiber because of smaller diameter.)
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What is the creep behavior in ceramics?
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At elevated temperature plastic deformation is time dependent. There is high resistance because of their high melting temperatures. This resistance can also be increased by increasing the grain size. It can be enhanced by adding a viscous grain boundary phase (add low melting temperature glass phase during powder processing of ceramics.)
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What are applications of refractory ceramics?
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These materials are used for heating elements, crucibles and furnace components.
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What are abrasive ceramics?
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These materials have high hardness and wear resistance. Diamond is the hardest but most expensive. SiC, WC, Al2O3 and SiO2 are often used as this material.
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What is the application of cement?
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This material is used to bind aggregates chemically such as sand and gravel to create concrete.
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What are heat engines?
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Ceramics have advantage over metals in these applications because of higher operating temperature, wear resistance, corrosion resistance and lower density. The drawback for this application is the brittle fracture of ceramics (researching to improve Kic.) Si3N4, SiC and ZrO2 look promising.
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What is electronic packaging?
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In this application ceramics are used for heat dissipation and electrical insulation in packaging of integrated circuits (becoming increasingly more important with miniaturization of electronics.) BN, SiC and AlN are often used in this application.
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What are piezoelectric ceramics?
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These materials convert electrical energy into mechanical energy and vice versa, are used in microphones, sonar detectors and strain gauges and include BaTiO3, PbTiO3, PbZrO3, PZT and quartz.
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What are microelectromechanical systems (MEMS?)
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These devices are integrated systems combining both electrical and mechanical components, fabricated on Si using IC processing technologies (research being done on ceramics that are tougher, more refractory and more inert than Si.) Its applications include microsensors and microactuators. It is currently being used as an accelerometer in air bag systems in cars (collision detector.)
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What are ceramic ball bearings?
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These materials have the advantage of being used at higher speeds, less noisy, longer life and corrosion resistance. The challenge is in the their processing/fabrication. Its uses include inline skates, bicycles, high speed dental drills, surgical saws and food processing equipment.
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