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64 Cards in this Set

  • Front
  • Back
Rutherford
discovered the atomic nucleus
What experiments did rutherford perform to find the nucleus
he shot alpha rays through gold foil to see if the ray went all the way through. what he discovered was that 99.9% of them all went through but the rest bounced back.
What did the discovery of neutrons conclude?
It is how elements can have different isotopes.
What do electrons determine?
It determines the chemical properties of an element.
Atomic Number?
number of protons in nucleus: determines number of electrons so determines
the chemical identity of the atom
Mass number?
sum of protons and neutrons in the nucleus. Atoms with the same atomic
number but different mass numbers are isotopes of the same element
Avogadros number
"mole"
finds a usable weight of an element.
λ
wavelength
John Dalton
atomic theory
1808
used balance to weigh chemical reactions and their properties
What are the two parts to Dalton's atomic theory?
1. Atoms all have characterisic masses.
2. Atoms combine in fixed ratios
Lavoisier
fisrt to weigh chemical reaction
discredited the conservation of matter
balance was enabling technology
Proust
law of constant proportions
did similar experiment to lavoisier
William prout
1816
came up with half weights and isotopes
Volta
built the world's first battery
first supply of electrical current
How is Volta's battery constructed
by layering Zn and Cu interchangeably. The metals don't touch.
Discovery of X-Rays
Wilhem Rontgen
1895
noticed zinc sulfide glowed in a cathode ray tube and placed a piece of cardboard between a tube and the mineral still glowed.
Discovery of Radioactivity
1896
Bequerel
exposed minerals to sun, wrapped them in photographic film, developed them later. the film was exposed even though it was not in the sun.
What conclusion did henri bequerel come to?
That uranium minerals are radioactive
Marie Curie
A woman radiochemist that suspected other radioactive elements in uranium ore.
Extracted polonium and radium.
3 types of radiation
alpha rays
beta rays
gamma rays
alpha rays
very weak, fast He nuclei
beta rays
more penetrating fast electrons
gamma rays
very penetrating, very high energy. used in x-rays
ν
frequency
c
speed of light
should be a given constant
diffraction
classical experiment that shows the wave nature of light.
produce a series of light and dark fringes on a screen.
J.J Thompson
discovered electron
1897
J.J. Thompson's Cathode Ray Tube
used in t.v. to produce screen.
helped discovered the electron by measuring the charge/mass ratio
Millikan
1908-09
Performed oil-drop experiment
Oil drop experiment
determined the mass of electrons by measuring their charge.
Plum pudding model
a mass of positive and negatively charge particles.
ultraviolent catastrophe
classical wave theory predicts that the light emitted
from a heated body would contain increasing amounts of energy as the wavelength
gets shorter
could not determine why this happens
Conservation of matter
that the mass of reaction products is the sum of masses of the reagents, if
the experiment is done with sufficient care that all the reactants are accounted for.
Davy
Electrolysis
discovered alkaline metals
E = mc2
einestein's equation for the mass of energy
c=velocity of light
isotopes
atoms with identical properties but different masses
law of multiple porportions
when elements combine to form more than one compound, the ratio of combining masses fo one of the elements would always be in the ratio of small whole numbers
michael faraday
discovered electrical power current
Packing Fracture Curve
measurements of the tiny mass
differences (per atomic particle or nucleon) for the easy elements to analyze
Proust
demonstrated that for a given reaction the ratio of the reactant weights was a
constant
vacuum pumps
1880
led to the discovery that an electric current
could also be passed through a gas if a sufficiently high voltage was applied with the gas at a low
enough pressure
What are some examples of exothermic energy?
From the sun
Hydrogen bombs
Hopefully in the future hydrogen fusion reactors
What did Aston's packing fracture curve make scientists realize?
the enormity of the nuclear energy that could be released if, for example,
the heaviest nuclei could be broken up into smaller, lighter nuclei
What is produced when elements are fused together?
Energy
Why can nuclear fusion happen?
Because heavier nuclei are stable than the lighter ones and allow elements to fuse together to create heavier ones
Quantum Theory
energy is discret packets
challenges ultraviolent catastrophe
explains the power curve
Who first developed the quantum theory?
Max Planck 1900
Photoelectric effect
energy increases as wavelengths get shorter
the
maximum energy of the
electrons increases as the
wavelength of the light gets
shorter.
Key details of the photoelectric effect
1. electron current is proportional to the light intensity-but only if the wavelenght of light is shorter than some threshold
2. electron energy is proportional to 1/wavelength
Albert Einstein's explanation of photoelectric effect (1905)
light acts as a series of
particles (now called photons) with energies proportional to the frequency
photons
wave packets
Bohr
1913
applied quantum ideas to rutherford's nucleus
non radiating orbits
electrons orbit around nucleus
What did niels bohr suggest about the stable orbits around the nucleus of an atom?
had quantized angular
momentum
What happend when light is absorbed by atoms?
The electrons get excited and jump to a higher "n" value or higher shell away from the nucleus.
What happens when light is emitted by atoms?
The electrons jump to a lower shell closer to the nucleus.
De Broglie
standing waves
particles such as electrons might
have wave-like properties
uantized energy levels in atoms might have
some association with standing waves
suggested that particles should have a wavelength
Bohr
1913
applied quantum ideas to rutherford's nucleus
non radiating orbits
electrons orbit around nucleus
v
velocity
What did niels bohr suggest about the stable orbits around the nucleus of an atom?
had quantized angular
momentum
Heinsberg's uncertainty principle for energy/time
Electrons only exist in excited states for a
short time
covers a broad range
Heinsberg's uncertainty principle for position/momentum
If we squeeze an electron into a smaller region of
space (make Δx smaller) its momentum uncertainty Δp increases
total energy cannot be less than
the energy uncertainty
waves
characterized by their velocity, frequency, and length
When do standing waves form?
when a traveling wave is reflected so that the returning wave is exactly in phase with the arriving wave
Schrodinger
produced a wave equation which described an electron moving in 3
dimensions under the influence of the electrostatic attraction of the atomic nucleus