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17 Cards in this Set

  • Front
  • Back
Activation Energy
minimum energy needed to cause a reaction to begin
Heat of Reaction
heat of the products --- heat of the reactants
Sign of endothermic
+
Sign of exothermic
--
What do catalysts NOT change?
heat of reaction and equilibrium
-they only allow equilibrium to be achieved quicker
CIA
concentration increase away
-away from the side that has the added concentration
TIA
temperature increase away
-away from the side that has the heat
Reactions are driven towards higher/lower entropy?
higher(more randomness(
Reactions are driven towards higher/lower heat?
lower (exothermic reactions favored)
LeChatelier's Principle
A system at equilibrium will shift in a predictable way to try to relieve the stress applied
Three types of stress
-temperature
-concentration
-pressure (gas)
Spontaneous change
are changes that will occur under given conditions
Factors that affect spontaneous change
1.) Tendency to change to a condition of less energy
2.) Tendency to change to a condition of greater randomness
Tendency for lower energy (spontaneous change)
-Most spontaneous reactions are exothermic
-The activation energy for an exothermic reaction is less than the reverse endothermic reaction
Tendency for randomness (spontaneous change)
-Randomness is the disorder, or lack of regularity, in a system
-The measurement of disorder in a system is called entropy
-Increased disorder means increased entropy
Systems go from greater order to
greater disorder
What determines the rate of reaction?
1.) Enough energy
2.) Proper orientation