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53 Cards in this Set
- Front
- Back
Chemical Bond
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Force that holds two atoms together
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Cation
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Positive ion
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Anion
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Negative ion
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What ending is used to designate an anion?
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ide
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What is the purpose for forming ionic compounds?
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To achieve s2p6
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What do metals and nonmetals do?
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-metals- lose electrons to form s2p6 cations
-nonmetals- gain electrons to form s2p6 anions |
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Covalent Bond
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Nonmetal + Nonmetal
Most electronegative, pulls electrons closer |
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Ionic Bond
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Metal + Nonmetal
metal gives electrons, nonmetal takes electrons |
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Metallic Bond
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Metal + Metal
pure metal alloys |
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Psuedo Noble-Gas Formation
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Relatively stable electron structures developed by loss of electrons in certain elements of groups 1B, 2B, 3A, and 4A
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What are the electron configurations and oxidation states of groups 1A through 6A?
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1A - s1, 1+
2A - s2, 2+ 3A - s2p1, 3+ 4A - s2p2, 4+ 5A - s2p3, 5+ 6A - s2p4, 6+ |
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What is a salt?
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Metal + Nonmetal
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Binary Compound
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1 cation + 1 anion
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Ionic Bond
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The electrostatic force that holds oppositely charged particles together in an ionic compound
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Lattice Energy
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The energy required to separate one mole of the ions of an ionic compound
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Oxyanion
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Negatively charged polyatomic ion that contains oxygen
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What does the formula unit of an ionic compound show?
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The simplest ratio of the ions
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What is the overall charge of a formula unit for an ionic compound?
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Zero
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Ionic bonds generally occur between.....?
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Metal + Nonmetal
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Crystal Lattice
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A three dimensional arrangement of particles in an ionic solid
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What is the relationship between lattice energy and the strength of the attractive force holding ions in place?
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The more negative the lattice energy, the greater the force
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The formation of a stable ionic compound from ions is always __________.
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Exothermic
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What happens in an electron transfer involving a metallic atom and a nonmetallic atom during ion formation?
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The nonmetallic atom gains electrons from the metallic atom
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Properties of Ionic Compounds
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-high melting point
-high boiling point -hard -brittle -poor electrical conductivity when solid -good electrical conductivity when liquid |
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True or false? The crystal lattice of ionic compounds affects their melting and boiling points.
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True
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True or false? The lattice energy is the energy required to separate the ions of an ionic compound.
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True
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True or false? The energy of an ionic compound is higher than that of the separate elements that formed it.
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False
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True or false? Large ions tend to produce a more negative value for lattice energy than smaller ions do.
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False
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True or false? Ions that have larger charges tend to produce a more negative lattice energy than ions with smaller charges do.
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True
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Formula unit
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Simplest ratio of the ions represented in an ionic compound
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Monatomic Ion
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A one-atom ion
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Oxidation number
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Equals the number of electrons transferred from an atom of the element to form the ion
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Polyatomic Ions
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Ions made up of more than one atom
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How do you name the multiple oxyanions for an element?
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-Ion with more oxygen atoms ends with "ate"
-Ion with less oxygen atoms ends with "ite" |
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What if more than two oxyanions are formed?
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-Two first rules remain the same
-Oxyanion with the MOST begins with "per" and ends with "ate" -Oxyanion with the LEAST beigns with "hypo" and ends with "ite" |
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ClO4
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Perchlorate
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ClO3
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Chlorate
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ClO2
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Chlorite
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ClO
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Hypochlorite
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What are the rules for naming ionic compounds?
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1. name cation first, anion second
2. cations- use name of element 3. anions- use root name of element and end in "ide" 4. variable oxidation state metal- stock system |
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Name these elements using the old system: Fe2+, Fe3+
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Fe2+ = ferrous
Fe3+ = ferric |
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Name these elements using the old system: Cu+, Cu2+
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Cu+ = copprous
Cu2+ = coppric |
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Electron sea model
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All the metal atoms in a metallic solid contribute their valence electrons to form a "sea" of electrons
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Delocalized electrons
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Electrons present in the outer energy levels of a metallic solid
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Metallic Bond
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The attraction of a metallic cation for delocalized electrons
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What properties do delocalized electrons give metals?
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1. malleability
2. ductility 3. conductive 4. strong bonds 5. luster |
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What are the two types of alloys?
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1. substitutional alloy
2. interstitial alloy |
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Substitutional Alloy
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Atoms of original metal are replaced by other atoms of same size
ex: sterling silver |
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Interstitial Alloy
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Small holes (interstices) in matrix are filled with smaller atoms
ex: carbon steel |
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What do "ate" and "ite" translate to in the old system?
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ate = ic
ite = ous |
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Why are electrons in a metallic solid described as delocalized?
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Because they are not held by any specific atom and are free to move
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Binary compounds
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Contain a metallic cation and a nonmetallic anion
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Name these elements using the old system: Sn2+, Sn4+
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Sn2+ = Stannous
Sn4+ = Stannic |