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53 Cards in this Set

  • Front
  • Back
Chemical Bond
Force that holds two atoms together
Cation
Positive ion
Anion
Negative ion
What ending is used to designate an anion?
ide
What is the purpose for forming ionic compounds?
To achieve s2p6
What do metals and nonmetals do?
-metals- lose electrons to form s2p6 cations
-nonmetals- gain electrons to form s2p6 anions
Covalent Bond
Nonmetal + Nonmetal

Most electronegative, pulls electrons closer
Ionic Bond
Metal + Nonmetal

metal gives electrons, nonmetal takes electrons
Metallic Bond
Metal + Metal

pure metal alloys
Psuedo Noble-Gas Formation
Relatively stable electron structures developed by loss of electrons in certain elements of groups 1B, 2B, 3A, and 4A
What are the electron configurations and oxidation states of groups 1A through 6A?
1A - s1, 1+
2A - s2, 2+
3A - s2p1, 3+
4A - s2p2, 4+
5A - s2p3, 5+
6A - s2p4, 6+
What is a salt?
Metal + Nonmetal
Binary Compound
1 cation + 1 anion
Ionic Bond
The electrostatic force that holds oppositely charged particles together in an ionic compound
Lattice Energy
The energy required to separate one mole of the ions of an ionic compound
Oxyanion
Negatively charged polyatomic ion that contains oxygen
What does the formula unit of an ionic compound show?
The simplest ratio of the ions
What is the overall charge of a formula unit for an ionic compound?
Zero
Ionic bonds generally occur between.....?
Metal + Nonmetal
Crystal Lattice
A three dimensional arrangement of particles in an ionic solid
What is the relationship between lattice energy and the strength of the attractive force holding ions in place?
The more negative the lattice energy, the greater the force
The formation of a stable ionic compound from ions is always __________.
Exothermic
What happens in an electron transfer involving a metallic atom and a nonmetallic atom during ion formation?
The nonmetallic atom gains electrons from the metallic atom
Properties of Ionic Compounds
-high melting point
-high boiling point
-hard
-brittle
-poor electrical conductivity when solid
-good electrical conductivity when liquid
True or false? The crystal lattice of ionic compounds affects their melting and boiling points.
True
True or false? The lattice energy is the energy required to separate the ions of an ionic compound.
True
True or false? The energy of an ionic compound is higher than that of the separate elements that formed it.
False
True or false? Large ions tend to produce a more negative value for lattice energy than smaller ions do.
False
True or false? Ions that have larger charges tend to produce a more negative lattice energy than ions with smaller charges do.
True
Formula unit
Simplest ratio of the ions represented in an ionic compound
Monatomic Ion
A one-atom ion
Oxidation number
Equals the number of electrons transferred from an atom of the element to form the ion
Polyatomic Ions
Ions made up of more than one atom
How do you name the multiple oxyanions for an element?
-Ion with more oxygen atoms ends with "ate"
-Ion with less oxygen atoms ends with "ite"
What if more than two oxyanions are formed?
-Two first rules remain the same
-Oxyanion with the MOST begins with "per" and ends with "ate"
-Oxyanion with the LEAST beigns with "hypo" and ends with "ite"
ClO4
Perchlorate
ClO3
Chlorate
ClO2
Chlorite
ClO
Hypochlorite
What are the rules for naming ionic compounds?
1. name cation first, anion second
2. cations- use name of element
3. anions- use root name of element and end in "ide"
4. variable oxidation state metal- stock system
Name these elements using the old system: Fe2+, Fe3+
Fe2+ = ferrous
Fe3+ = ferric
Name these elements using the old system: Cu+, Cu2+
Cu+ = copprous
Cu2+ = coppric
Electron sea model
All the metal atoms in a metallic solid contribute their valence electrons to form a "sea" of electrons
Delocalized electrons
Electrons present in the outer energy levels of a metallic solid
Metallic Bond
The attraction of a metallic cation for delocalized electrons
What properties do delocalized electrons give metals?
1. malleability
2. ductility
3. conductive
4. strong bonds
5. luster
What are the two types of alloys?
1. substitutional alloy
2. interstitial alloy
Substitutional Alloy
Atoms of original metal are replaced by other atoms of same size
ex: sterling silver
Interstitial Alloy
Small holes (interstices) in matrix are filled with smaller atoms
ex: carbon steel
What do "ate" and "ite" translate to in the old system?
ate = ic
ite = ous
Why are electrons in a metallic solid described as delocalized?
Because they are not held by any specific atom and are free to move
Binary compounds
Contain a metallic cation and a nonmetallic anion
Name these elements using the old system: Sn2+, Sn4+
Sn2+ = Stannous
Sn4+ = Stannic