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48 Cards in this Set
- Front
- Back
What is an exothermic reaction? |
One which gives out energy usually in heat
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How is an exothermic reaction shown?
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A rise in temperature
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What is an example of an exothermic reaction?
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Combustion
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What is an endothermic reaction?
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One that takes in energy, usually in heat
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How is an endothermic reaction shown?
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A fall in temperature
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What is an example of an endothermic reaction?
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Thermal decomposition
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How do you decide whether a reaction is endo or exo?
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You can measure the amount of energy produced by taking the temperature of the reactants and mix in a polystyrene cup and measure the temperature of the solution at the end
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What happens during a chemical reaction?
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Old bonds are broken and new bonds are formed
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Is bond breaking an exothermic or an endothermic reaction?
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Endothermic because energy is supplied
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Is bond making an exothermic or an endothermic reaction?
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Exothermic because it releases energy when formed
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Explain the calorimetric method ued to measure the energy content of fuels
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1. Reduce draughts so as much heat as possible goes into heating the water eg. use a screen
2. Put fuel in spirit burner and weigh 3. Measure water into a copper calorimeter 4. Take initial temperature of water and light wick 5. When water temperature has raised by 20-30 degrees, note the highest temperature of water 6. Reweigh the burner 7. Repeat if comparing fuels |
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What is the equation for energy given out per gram?
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Energy per g = energy released / mass of fuel burnt
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Name 4 ways to keep the calorimetric test fair
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Same equipment
Same amount of water Water initial and final temperatures = same Repeat |
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Give an example of a slow chemical reaction?
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Rusting
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Give an example of a fast chemical reaction?
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Burning
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The rate of reaction that produces a gas can be observed by measuring how quickly the gas is produced. Name two ways of doing this.
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- Measure the change in mass = mass falls as gas produced
- Measure cm(cubed) of gas given off = gas syringe Must do these at regular intervals |
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What two things does the rate of reaction depend on?
Explain why |
Collision frequency = more collisions = faster
Energy transferred in collision = enough energy to be successful |
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What effect does an increase in temperature have on collisions?
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They move quicker = more collisions
Increases energy of collisions = more successful collisions |
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What effect does an increase in concentration or pressure have on collisions?
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More particles in the same space = closer together = more collisions
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What effect does an increase in surface area have on collisions?
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More surface area exposed = more area to work on = collisions will increase
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What effect does a catalyst have on collisions?
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Provides surface where reactions can take place.
Lowers the activation energy (reduces the energy needed by particles to react) |
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What is the equation for atom economoy?
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Atom economoy = Total Mr of desired products / Total Mr of all products (x100)
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Why does a high atom economy benefit the environment?
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Reactions with low atom economy use up resources very fast
Make lots of waste = has to be disposed of = unsustainable |
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How does atom economy effect profits?
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The lower the atom economy = aren't profitable because expensive to buy materials and waste products can be expensive to dispose responsibly of
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What is the equation for percentage yield?
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Percentage yield = actual yield (g) / predicted yield (g)
(x100) |
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Give four reasons for why yields are always less than 100%?
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- Evaporation
- Filtration (solid/liquid some left behind) - Transferring liquids (some remain on inside of old container) - Not all reactants make a product |
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Give 2 advantages of batch production
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Flexible = several different products made using the same equipment
Low start up costs |
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Give 2 disadvantages of batch production
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Labour intensive
Difficult to obtain the same quality in each batch |
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Give 3 advantages of continuous production
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Never stops = no time is wasted emptying reactors and setting up again
Runs automatically Quality is always consistent |
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Give a disadvantage of continous production
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Start up costs are very high
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Give an example of a product made by batch production
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Pharmaceutical drugs
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Give an example of a product made by continous production
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Ammonia (haber process)
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What is the pharmaceutical drug making process?
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- Research and development
- Testing/trialling to ensure it works and is safe - Manufacture |
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What two things make drugs expensive to make?
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- Raw materials (extracted from plants)
- Energy |
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How do you extract a substance from a plant?
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It has to be crushed, boiled and dissolved in a suitable solvent
Then use chromatography to extract the substance you want |
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How can you tell if a substance is pure with chromotography?
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It won't be seperated by chromotography (one blob)
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How can you tell if a substance is pure by the boiling/melting points of thesubstance?
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They have specific melting points
If a substance is impure, the melting point will be too low and the boiling point too high |
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Give four properties of diamond
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Lustrous
Colourless Strong covalent bonds = high melting point Doesn't conduct electricity |
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What makes diamond very hard?
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Each carbon atom forms four covalent bonds in a very rigid giant covalent structure = very hard
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Why is diamond useful as a cutting tool?
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-Really hard because of giant covalent structure
-Has a high melting point |
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Give five properties of graphite
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Black
Opaque Shiny High melting point Conducts electricity |
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Explain the structure of graphite
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Each carbon atom only forms three covalent bonds, creating sheets of carbon atoms which are free to slide over each other
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Why can graphite conduct electricity?
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Since only 3 out of each carbons 4 outer electrons are used in bonds, there are lots of delocalised electrons which move
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What three properties do all giant molecular structures share?
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Strong, high melting points and don't dissolve in water
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What are fullerenes?
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Molecules of carbon shaped like closed tubes/hollow balls
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What is a use of a fullerene?
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To "cage" other moleculs = eg. new way of delivering a drug to the body for slow release?
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What can fulluerenes be joined together to make?
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Nanotubes which are tiny hollow carbon tubes
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What is a use of a nanotube?
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Have a large surface area = industrial catalysts
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