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23 Cards in this Set
- Front
- Back
what is the octet rule?
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when bonding, atoms tend to reach an electron arrangement with 8 electrons in outer shell.
exceptions are: transition metals, gases near helium (have 2 in outer shell) |
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what is an ionic bond?
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the force of attraction between oppositely charged ions in a compound
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what is a transition metal?
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an element that forms at least one ion with a partially filled d-sublevel
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why are Sc and Zn not part of the transition metals?
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Sc and Zn...
do not have a variable valency produce white compounds not used as catalysts |
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what is a molecule?
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a group of atoms joined together. it is the smallest part of an element or compound that can exist independently
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what is a covalent bond?
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the chemical bond formed by sharing a pair of electrons
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using the valence shell electron pair repulsion theory to determine the shape of the molecule
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-determine what the central atom is
-use periodic table to determine no. of bond pairs -the group the element is in will determine e- in outer orbit -subtract no. bond pairs leaving lone electrons |
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define electronegativity
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the relative attraction an atom in a molecule has for a shared pair of electrons in a covalent bond. delta indicates slightly + or -
measured by Pauling. It is the measure of the amount of energy needed to break a bond |
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what is intramolecular bonding?
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bonding between 2 atoms within a molecule/particle
ie. ionic bond, covalent bond (polar, weakly polar, non-polar) |
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what is intermolecular bonding?
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bonding between molecules
eg, Van der Waals forces dipole-dipole forces hydrogen bonding |
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how to find if compound is ionic or covalent using electronegativity values
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if difference is > 1.7 then ionic
if < 1.7 then covalent |
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what is the valency of an element?
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the number of atoms of Hydrogen (a monovalent element) which will bond with an atom of that electron
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shapes of molecules
no. of bond pairs=1 no. of lone pairs= N/A |
linear
AB 180' |
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shapes of molecules
no. of bond pairs=2 no. of lone pairs=0 |
linear
AB2 180' |
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shapes of molecules
no of bond pairs=3 no. of lone pairs=0 |
triangular planar
AB3 120' |
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shapes of molecules
no. of bond pairs=4 no. of lone pairs=0 |
tetrahedral
AB4 109.5' |
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shapes of molecules
no. of bond pairs=3 no. of lone pairs=1 |
pyramidal
AB3 107' |
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shape of molecules
no. of bond pairs=2 no. of lone pairs=2 |
v-shaped
AB2 104.5' |
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explain van der waals forces
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exist between non-polar molecules. week forces of attraction. formed due to temporary dipoles being formed as moving electrons are momentarily at one end of the molecule
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explain dipole-dipole forces
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forces of attraction which exist between the negative pole of one molecule and the positive pole of another. stronger than van der waals
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explain hydrogen bonds
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special dipole-dipole forces that exist when hydrogen bonds with nitrogen, oxygen, or fluorine. the strong positive charge on the hydrogen acts as a bridge between the two electronegative atoms
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melting and boiling points of ionic compounds
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usually solids at room temperature. very high melting and boiling points caused by the very strong forces of attraction between oppositely charged ions
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melting and boiling points of covalent compounds
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depends on two aspects
-the intermolecular forces (eg van der waals) -the relative atomic mass (Mr) of the compound |