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93 Cards in this Set
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Atomic number |
The number of protons in the nucleus of an atom |
Protons in |
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Mass Number |
The number of protons and neutrons in the nucleus of an atom |
Number of isotopes |
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Isotopes |
Atoms of the same element (same number of protons and electrons) With a different number of neutrons |
Atoms of |
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Atomic orbital |
Region around the nucleus that can hold up to two electrons, with opposite spins |
A region around |
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P block element |
Element which has the highest energy electron in a p sub shell |
Element which |
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First ionisation energy |
The energy required to remove One electron from each atom in One mole of gaseous atoms to form one mole of gaseous 1+ ions kjmol |
Energy required |
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Successive ionisation energy |
Measure of the energy required to remove one electron in turn |
In turn |
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Acid |
Proton donor |
Donor |
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Base |
Proton acceptor |
Acceptor |
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Alkali |
Base that dissolves in water and releases 0H- ions in aqueous solution |
OH- |
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Salt |
Compound produced when a H+ ion from an acid is replaced with a metal ion or another positive ion such as an ammonium ion |
Replaced |
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Molar Mass |
The mass in grams per mole of a substance gmol |
In G |
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Relative isotopic mass |
The mass of an atom of an isotope compares with 1/12 the mass of an atom of carbon 12 |
Of an atom |
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Relative atomic mass |
The weighted mean mass of an atom of an element compared with 1/12 of the mass of an atom of carbon 12 |
Weighted |
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Mole |
Amount of substance containing as many particles as there are carbon atoms in exactly 12 g of carbon 12 |
Amount |
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Avogadro's constant |
Number of particles per mole of a substance 6.02×10^23 |
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Empirical formula |
The Simplest whole number ratio of atoms of each element present in a compound |
Ratio |
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Molecular formular |
The actual number of atoms of each element in a molecule |
Actual |
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Water of crystallisation |
Water present in a compound giving the compound a crystalline appearance |
Appearence |
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Water of crystallisation |
Water present in a compound giving the compound a crystalline appearance |
Appearence |
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Anhydrous |
When all the water of crystallisation have been removed from a compound |
Removed |
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Water of crystallisation |
Water present in a compound giving the compound a crystalline appearance |
Appearence |
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Anhydrous |
When all the water of crystallisation have been removed from a compound |
Removed |
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Hydrated |
When water of crystallisation is present in a compound |
When |
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Metallic bonding |
Strong electrostatic attraction between metal cations (positive ions) and delocalised electrons (The giant metallic lattice structure) |
Electrostatic |
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Ionic Bond |
The electrostatic attraction between oppositely charged ions |
Between |
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Covalent bond |
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms |
Strong |
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Covalent bond |
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms |
Strong |
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Dative co-ordinate bond |
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonding atoms, where one of the atoms supply is both of the electrons shared |
Both |
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Covalent bond |
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms |
Strong |
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Dative co-ordinate bond |
Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonding atoms, where one of the atoms supply is both of the electrons shared |
Both |
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Electronegativity |
The ability of an atom to attract bonding electrons towards itself in a covalent bond |
Bonding electrons |
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Electron pair repulsion theory |
• electron pairs repel each other as far apart as possible • lone pairs of electrons repel more stronger than bonding pairs of electrons |
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Oxidation number |
A measure of the number of electrons that an atom uses to bond atoms of another element |
Uses |
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Oxidation |
Loss of electrons and increase in oxidation number |
Loss |
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Reduction |
Gaining electrons and loss in oxidation number |
Gain |
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Oxidising agent |
Reagent that oxidises another species (Itself reduced) |
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Oxidising agent |
Reagent that oxidises another species (Itself reduced) |
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Reducing agent |
A Reagent that reduces another species (itself oxidised) |
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Redox |
Reaction were both oxidation and reduction take place |
Both |
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Periodicity |
Repeating trends in the physical and chemical properties across different periods |
Repeating trends |
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Displacement reaction |
A reaction in which a more reactive element (halogen) displaces a less reactive element (halogen) from an aqueous solution of its halide ions |
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Disproportionation |
Reaction in which the same element is oxidised and reduced |
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Enthalpy Change |
Amount of heat released or absorbed Chemical reaction, carried out under constant pressure Kjmol-1 |
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Enthalpy Change |
Amount of heat released or absorbed Chemical reaction, carried out under constant pressure Kjmol-1 |
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Exothermic reaction |
Reaction in which heat energy is released into the surroundings ( H- ) |
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Endothermic reaction |
A reaction in which heat energy is absorbed from the surroundings |
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Average bond enthalpy |
Average enthalpy change when one mole of gaseous bonds are broken by homolytic fission |
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Standard conditions |
•25° C or 298K • 1 atmosphere pressure or 100kPa • 1.0dm^3 concentration |
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Standard states |
Physical states under standard conditions |
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Standard states |
Physical states under standard conditions |
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Standard enthalpy change of a reaction |
The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard states. |
Accompanies |
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Standard enthalpy change of neutralisation |
Change that accompanies the neutralisation of an aqueous acid by an aqueous base form one mole of H2O under standard conditions |
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Standard enthalpy change of formation |
The Enthalpy change when One mole of a compound is formed from its constituent elements in their standard states under standard conditions |
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Standard enthalpy change of combustion |
The enthalpy change when one mole of a substance reacts completely with oxygen understand the conditions all products and reactants in their standard states |
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Hess' Law |
The enthalpy change of reaction depends only on the initial and final states and is independent on the route taken |
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Activation energy |
Minimum energy required to start a reaction by the breaking of bonds in the reactants |
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Activation energy |
Minimum energy required to start a reaction by the breaking of bonds in the reactants |
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Catalyst |
Increases the rate of reaction without being used up by the overall reaction |
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Hydrocarbon |
Compounds containing only hydrogen and carbon |
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Homologous series |
Series of organic compounds having the same functional group but with each successive member differing by CH2 |
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Structural isomers |
Compounds with the same molecular formula but different structural formula |
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Structural isomers |
Compounds with the same molecular formula but different structural formula |
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Stereo isomerism |
Compounds with the same structural formula but different arrangement of atoms in space |
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Structural isomers |
Compounds with the same molecular formula but different structural formula |
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Stereo isomerism |
Compounds with the same structural formula but different arrangement of atoms in space |
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E/Z isomerism |
An example of stereoisomerism in which there is a restricted rotation around a C=C double bond, and each of the CC double bond have two different groups attached to it. |
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Cis/Trans Isomerism |
A special case of ez isomerism in which there is a hydrogen atom on each carbon atom of the CC double bond |
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Radical |
Species with an unpaired electron |
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Curly arrow |
The movement of an electron pair showing either heterolytic fission or the formation of a covalent bond |
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Electophile |
Electron pair acceptor |
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Nucleophile |
Electron pair donor |
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Substitution reaction |
Reaction where atom or group in a molecule is replaced by another atom or group |
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Addition reaction |
Reaction where a group is added over the double bond of another atom or group |
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Elimination reaction |
Reaction where an atom or group is removed from a molecule to make an unsaturated molecule |
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Oxidation reaction |
Reaction where oxygen is added and/or hydrogen is removed from a molecule |
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General formula |
CnH2n+2 |
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Structural formula |
CH3CH2CH3 |
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Displayed formula |
Showing all the bonds |
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Skeletal formula |
Showing the bonds only and functional groups |
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Functional group |
A group of atoms within a molecule responsible for the characteristic reactions of a compound |
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Aliphatic |
Compound containing carbon and hydrogen join together in straight chains, branched chains or non-aromatic rings |
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Alicyclic |
And aliphatic compound arranged and non-aromatic rings with or without sidechains |
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Aromatic Chem |
Compound containing a benzene ring |
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Condensation reaction |
A reaction where a H2O molecule is lost when two molecules are joined together |
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Dehydration reaction |
A reaction where a H2O molecule is removed from a saturated molecule to form an unsaturated molecule |
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Hydrolysis reaction |
Chemical reaction involving water or an aqueous solution, which causes the breaking of a bond, splitting a reactant molecule into two products |
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Sigma Bond |
Single end-on (axial) overlap of orbitals directly between bonding atoms, allowing free rotation of the bond |
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Pi Bond |
Double sideways overlap of adjacent P orbitals above and below the plane of bonding atoms, with restricted rotation of the bond |
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Volatility |
Ease with which a liquid turns into a gas |
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Precipitate |
And insoluble solid formed when two solutions are mixed together |
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Distillation |
Is the technique of heating a liquid to create vapour which is collected when cooled and condensed, separate from the original liquid |
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Heat under reflux |
The continuous boiling and condensing of the liquid preventing loss of volatile liquids from a heated reaction vessel |
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