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27 Cards in this Set

  • Front
  • Back

Define equilibrium

In a closed system


The forward and backward reactions


Occur at the same rate

Functional group: alcohol

-OH

Functional group: carboxylic acid

-COOH

Functional group: esther

-COO-

Number of moles =

Concentration =

Define electrolyte

The substance broken down in electrolysis



A liquid containing free moving ions, that is broken down by electricity in the process of electrolysis

In which form is the electrolyte?

Molten or in solution, so the ions are free to move

When does electrolysis take place?

When a current is passed through the:


Molten ionic compound


OR


The solution containing ions

What are the electrodes made from?

An inert substance

Why are the electrodes made from the type of material that they are made from?

So they do not react with the products

What is produced at the anode (+ve) when an aqueous solution is electrolysed?

Oxygen gas


UNLESS


halides are present

What is produced at the cathode (-ve) when an aqueous solution is electrolysed?

Hydrogen gas


UNLESS


the solution contains metal ions that are LESS reactive that hydrogen

What is the ore of aluminium?

Bauxite (aluminium oxide)

What is added to aluminium to make it melt at a lower temperature?

It is mixed with molten cryolite

Why do carbon anodes need to be replaced regularly in the electrolysis of aluminium?

At high temperatures, the oxygen from the bauxite reacts with the carbon anodes to form carbon dioxide, so they gradually burn away

What are the products of the electrolysis of brine?

Hydrogen gas


Chlorine gas


Sodium hydroxide solution

What are the uses of the products of the electrolysis of brine?

Hydrogen - margarine, HCl


Sodium hydroxide - soap, bleach, paper, control pH (strong alkali)


Chlorine - bleach, kill bacteria in water

What is electroplating?

Using electrolysis to place a thin layer of metal onto an object

Benefits of electroplating

Aesthetics



Protects a metal from corroding



Increases the hardness of a surface



Reduce costs by using a thin layer of an expensive metal rather than making the whole object from the pure metal

Which electrode is the object being electroplated placed as?

Cathode (-ve)

Describe phytomining

Plants are grown in soil which contains copper



As the plant takes up nutrients from the soil, copper also builds up in the plant's tissue



The plant is harvested, dried, and burnt in a furnace



Copper is collected from the ash of the plant using scrap iron (displacement) and electrolysis

Benefits of phytomining and bioleaching

Copper can be obtained from low grade ores. Copper-rich ores are less available

Disadvantages of phytomining and bioleaching

They are slow processes

Describe bioleaching

Bacteria feed on low grade copper ores



Through both biological and chemical processes, a solution of copper ions (leachate) is obtained



Scrap iron (displacement) and electrolysis is used to extract the copper from solution

What is the catalyst for the haber process?

Iron

What is the catalyst for cracking?

Zeolite or porcelain