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31 Cards in this Set

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Combustion Reaction

Heat + Fuel + O2 ——> Heat + Light + New Products

When does Complete Combustion occur?

When Fuel, O2 and Heat are in perfect ratios (very rare).

What is it called when fuel, heat and O2 ratios are not perfect in the combustion reaction?

Incomplete reaction

What incomplete combustion occurs what new products can be created?

Carbon Monoxide, Hydrogen Cyanide, Ammonia, Solid Particles

What are the 3 (general) states of matter?

Solid — Liquid — Gas

What is pyrolysis?

The chemical decomposition of a substance when heat is applied.

What is created when pyrolysis occurs?

Highly flammable vapours.

When more heat is applied to a substance the rate of pyrolysis...

Increases

How does surface area influence how something burns?

As surface area increases the rate it burns also increases because it will more readily absorb heat, breakdown and ignite.

What must occur for liquid to burn?

They must Vaporise.

Flash point is defined as...

The lowest temperature that a liquid will give off enough flammable vapours to produce a flash on the application of an ignition source but will not continue to burn once the ignition source is removed.

Fire Point is defined as...

The lowest temperature that liquid will give off enough flammable vapours in air to produce a flash on the application of an ignition source and then continue to burn once ignition source has been removed.

Specific Gravity is defined as...

Measure of density of a liquid in comparison to water.


Water = 1

Fire Point is generally how many degrees higher than its Flash Point?

10

Polar Solvents are defined as...

Flammable liquids that mix with water.

If a liquid has a specific gravity less than one it will....

Float on water

Do gaseous fuels need to change state to burn?

No

Vapour Density is defined as...

Measure of density of a vapour against air.


Air = 1

If a gas has a density less than 1 will it settle in low areas?

No because it is lighter than air.

Flammability Range is defined as...

For a flammable fuel and air mixture to burn, its concentration must lie between two limits.

The 3 flammability range limits are?

Lower Flammability Limit (LFL)


Upper Flammability Limit (UFL)


Ideal Mixture

The LFL is defined as...

The minimum concentration of a fuel to air which will support combustion.

The UFL is defined as...

The maximum concentration of fuel to air which will support combustion.

Ideal Mixture if defined as...

A point between the LFL and UFL which has the ideal proportions of fuel to air.

A mixture with too much fuel to air is know as ‘too rich’ or ‘too lean’?

Too Rich

What happens to the LFL and UFL when temperature is increased?

They both widen.

What happens to the LFL and UFL in areas with enriched Oxygen concentration?

The LFL remains steady and the UFL will increase. Therefore increasing the flammability range.

The 3 types of heat transfer are?

Convection - transfer of heat through movement of air or liquid.


Conduction - heat transfer through a solid by the collision of molecules.


Radiation - heat transfer through electromagnetic waves.

3 stages of Fire Development are...

1) Growth - once flaming combustion occurs and the fire has sufficient fuel and oxygen available.


2) Fully Developed - the fire has developed as far as the fuel and oxygen supply will allow.


3) Decay - slowing of combustion due the consumption of available fuel.

How can fires be extinguished?

Removal of one or more elements of the fire tetrahedron.


Heat


Fuel


Oxygen


Chemical Chain Reaction

Taking away one or more elements of the fire tetrahedron can be achieved by:

Cool - removal of HEAT


Starve - removal or separation of unburnt FUEL


Smother - remove/dilute OXYGEN supply


Inhibiting the Chemical Chain Reaction at a chemical level e.g. Dry Chem Powder.