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44 Cards in this Set

  • Front
  • Back
Alkenes to Halogenoalkanes
(Reagent, condition and type of reaction)



Alkenes to Halogenoalkanes


(Reagent, condition and type of reaction)


Hydrogen bromide/HBr


Room temperature


Nucleophilic addition Reaction

Alkenes to Alkanes
2x (Reagent, catalyst, conditions and type of reaction)

Alkenes to Alkanes


2x (Reagent, catalyst, conditions and type of reaction)

Nucleophilic addition Reaction


1) Hydrogen gas, very fine nickle catalyst, 150 degrees and 50 atmospheres


OR


2) Hydrogen gas, platinum catalyst, at room temperature

Alkenes to Halogenoalkanes

Alkenes to Halogenoalkanes

Hydrogen bromide/HBr


Room temperature


Nucleophilic addition Reaction

Alkenes to Alkanes

Alkenes to Alkanes

Nucleophilic addition Reaction


1) Hydrogen gas, very fine nickle catalyst, 150 degrees and 50 atmospheres


OR


2) Hydrogen gas, platinum catalyst, at room temperature

Alkane to Halogenoalkane
(Type of reaction, reagent and conditions)

Alkane to Halogenoalkane


(Type of reaction, reagent and conditions)

Radical Substitution


Bromine liquid/Br2(l)/Halogen


UV or Sunlight

Alkane to Halogenoalkane

Alkane to Halogenoalkane

Radical Substitution


Bromine liquid/Br2(l)/Halogen


UV or Sunlight

Halogenoalkane to Amine
(Type of reaction, reagent and conditions)

Halogenoalkane to Amine


(Type of reaction, reagent and conditions)

Nucleophilic substitution,

Concentrated NH3(aq)/ammonia


Heat in sealed tube


Amines can act as bases/proton acceptors forming NH3+

Halogenoalkane to Amine

Halogenoalkane to Amine

Nucleophilic substitution,


Concentrated NH3(aq)/ammonia


Heat in sealed tube


Amines can act as bases/proton acceptors forming NH3+

Halogenoalkane to nitrile
(Type of reaction, reactant and conditions)

Halogenoalkane to nitrile


(Type of reaction, reactant and conditions)

Nucleophilic substitution, NaCN in aqueous ethanol solution, heat under reflux

Halogenoalkane to nitrile

Halogenoalkane to nitrile

Nucleophilic substitution, NaCN in aqueous ethanol solution, heat under reflux

Nitrile to carboxylic acid
(type of reaction, reagents, and conditions)

Nitrile to carboxylic acid


(type of reaction, reagents, and conditions)

Hydrolysis reaction with H+ ions/ water and heat under reflux

Nitrile to carboxylic acid

Nitrile to carboxylic acid

Hydrolysis reaction with H+ ions/ water and heat under reflux

Halogenoalkane to alcohol
(Type of reaction, reagents and conditions)

Halogenoalkane to alcohol


(Type of reaction, reagents and conditions)

Nucleophilic substitution, NaOH(aq), heat under reflux with ethanol

Halogenoalkane to alcohol

Halogenoalkane to alcohol

Nucleophilic substitution, NaOH(aq), heat under reflux with ethanol

Alcohol to halogenoalkane

Alcohol to halogenoalkane


(Type of reaction, reagents and conditions)

Nucleophilic substitution, NaBr(s), concentrated sulphuric acid, heat under reflux



Alcohol to halogenoalkane

Alcohol to halogenoalkane

Nucleophilic substitution, NaBr(s), concentrated sulphuric acid, heat under reflux

Alcohol to Alkene
(Type of reaction, 3x reagents and conditions) 

Alcohol to Alkene


(Type of reaction, 3x reagents and conditions)

Elimination Reaction


1) Al2O3 (s) at 300 degrees


2) Concentrated sulphuric acid, heat under reflux followed by water


3) Ethanol vapours over phosphoric acid, steam 300 degrees, at 60 atm

Alcohol to Alkene

Alcohol to Alkene

Elimination Reaction

1) Al2O3 (s) at 300 degrees


2) Concentrated sulphuric acid, heat under reflux followed by water


3) Ethanol vapours over phosphoric acid, steam 300 degrees, at 60 atm

Alcohol to Aldehyde
(Type of reaction, reagents and conditions)

Alcohol to Aldehyde


(Type of reaction, reagents and conditions)

Oxidation reaction


Cr2O7 2- / H+(aq)


Distillation





Alcohol to Aldehyde

Alcohol to Aldehyde

Oxidation reaction


Cr2O7 2- / H+(aq)


Distillation

Aldehyde to Alcohol
(Type of reaction and reagents)

Aldehyde to Alcohol


(Type of reaction and reagents)

Reduction


NaBH4



Aldehyde to Alcohol

Aldehyde to Alcohol

Reduction


NaBH4

Aldehyde to Carboxylic acid 
(Type of reaction, reagents and conditions)

Aldehyde to Carboxylic acid


(Type of reaction, reagents and conditions)

Oxidation reaction


Cr2O7 2- / H+(aq)


Heat under reflux



Aldehyde to Carboxylic acid 

Aldehyde to Carboxylic acid

Oxidation reaction


Cr2O7 2- / H+(aq)


Heat under reflux

Carboxylic acid to ester
(Type of reaction x 2, reagent, catalyst and conditions)

Carboxylic acid to ester


(Type of reaction x 2, reagent, catalyst and conditions)

Esterification/Condensation

R'OH/phenol with concentrated sulphuric acid catalyst


Heat under reflux

Carboxylic acid to ester

Carboxylic acid to ester

Esterification/Condensation


R'OH/phenol with concentrated sulphuric acid catalyst


Heat under reflux

Ester to Carboxylic acid
(Type of reaction and reagents)

Ester to Carboxylic acid


(Type of reaction and reagents)

Hydrolysis


H+ (aq)/ H2O



Ester to Carboxylic acid

Ester to Carboxylic acid

Hydrolysis


H+ (aq)/ H2O

Carboxylic acid to acyl chloride
(Type of reaction, reagent and conditions)

Carboxylic acid to acyl chloride


(Type of reaction, reagent and conditions)

Nucleophilic substitution


SCl2O


Heat under reflux in anhydrous conditions

Carboxylic acid to acyl chloride

Carboxylic acid to acyl chloride

Nucleophilic substitution


SCl2O


Heat under reflux in anhydrous conditions

Acyl chloride to Ester
(Type of reaction, reagent and conditions)

Acyl chloride to Ester


(Type of reaction, reagent and conditions)

Acylation


R'OH/Phenol


Room temperature in anhydrous conditions



Acyl chloride to Ester

Acyl chloride to Ester

Acylation


R'OH/Phenol


Room temperature in anhydrous condition

Acyl chloride to primary amide
(Type of reaction, reagent and conditions)

Acyl chloride to primary amide


(Type of reaction, reagent and conditions)

Acylation


Concentrated ammonia/NH3 (aq)


Room temperature in anhydrous condition



Acyl chloride to primary amide

Acyl chloride to primary amide

Acylation


Concentrated ammonia/NH3 (aq)


Room temperature in anhydrous condition

Acyl chloride to secondary amide
(Type of reaction, reagent and conditions)

Acyl chloride to secondary amide


(Type of reaction, reagent and conditions)

Acylation


R'NH2


Room temperature in anhydrous condition

Acyl chloride to secondary amide 

Acyl chloride to secondary amide

Acylation


R'NH2


Room temperature in anhydrous condition

Primary amide in acid/alkali conditions
(Type of reaction and conditions)

Primary amide in acid/alkali conditions


(Type of reaction and conditions)

Hydrolysis
Heat under reflux with either H+ (aq) or OH-(aq)

Hydrolysis


Heat under reflux with either H+ (aq) or OH-(aq)



Primary amide in acid/alkali conditions

Primary amide in acid/alkali conditions

Hydrolysis
Heat under reflux with either H+ (aq) or OH-(aq)

Hydrolysis


Heat under reflux with either H+ (aq) or OH-(aq)

Secondary alcohol to ketone
(Type of reaction, reagents and conditions)

Secondary alcohol to ketone


(Type of reaction, reagents and conditions)

Oxidation reaction


Cr2O7 2-/H+ (aq)


Heat under reflux

Secondary alcohol to ketone

Secondary alcohol to ketone

Oxidation reaction


Cr2O7 2-/H+ (aq)


Heat under reflux

Ketone to Secondary alcohol
(Type of reaction and reagent)

Ketone to Secondary alcohol


(Type of reaction and reagent)

Reduction reaction


NaBH4

Ketone to Secondary alcohol

Ketone to Secondary alcohol

Reduction reaction


NaBH4

Ketone to Cyanohydrin
(Type of reaction and reagents)

Ketone to Cyanohydrin


(Type of reaction and reagents)

Nucleophilic Addition


HCN and a small amount of OH-

Ketone to Cyanohydrin

Ketone to Cyanohydrin

Nucleophilic Addition


HCN and a small amount of OH-