Sulfur Brown 4,5,14,53,62. Sulfur Brown 14 is obtained by heating o- or p-(2,4-dinitroanilino)phenol with caustic soda and water to 105⁰C and then add dextrose, sodium sulfide and sulfur. Sulfurization temperature may vary from 123⁰C (under reflux) to 160⁰C (bake). Dyes from substituted naphthalenes: Brown dyes of this type include C.I. Sulfur Brown 7,15,16,31,63. Sulfur Brown 15 is obtained by Obtained by baking a mixture of 138 parts of 1,5-dinitronaphthalene and 75 parts of crude cresol with sodium polysulfide, in the presence of copper sulfate and sodium chloride at 265⁰C for 12-14 hours.…
The solution was stirred and cooled to 0°C using a water bath. The flask was removed from the ice bath then household beach (4%, 272.2ml, 1.2equiv) was added to the solution while stirring vigorously. Solution changed from colourless to dark red-brown to pale yellow. After a short time, sodium thiosulfate (10%, 10ml) was added. HCL (10%, 10ml) was added to acidify the reaction.…
Based on the Thin Layer Chromatography results, my experiment was successful. Throughout the experiment, TLC was used to monitor the oxidation process, while the solution was being heated in the hot water bath.6 9-fluorenol is oxidized when the acetic acid transforms the hypochlorite into hypochlorous acid.6 A carbonyl is formed as a result of the hypochlorous acid acting as a nucleophile.6 The last TLC plate was used to identify and check the purity of my product by comparing Rf values.7 My TLC plate confirmed that my product was 9-fluor My percentage yield, however, was not successful. The calculated percentage was 207.2% with a product weight of 0.208 g. The cause of this result could be from not removing enough water using sodium sulfate. It could also be caused by a mistake made while separating the aqueous layer from the hexane layer in the separatory funnel.…
The objective of this experiment was to oxidize 9-fluorenol with bleach to form 9-fluorenone. This was done with three different reactions, each under different conditions. The reactions were evaluated using the TLC plate to see how far each reaction progressed. During the experiment reaction test tube 2 had the darkest yellow color out of the three reactions.…
In this lab, benzoic acid, benzocaine, and 9-fulorenone are isolated from a three-component mixture by using the acid-base extraction and other following types of various extraction techniques. An acid-base reaction is utilized in order to isolate the individual species from the mixture. First, in isolating the base benzocaine, proton transfers occurred via reaction with hydrochloric acid, which led to a significant shift in the polarity of the said compound, although the conjugate acid of benzocaine formed as a result. Due to the change in polarity, the state of benzocaine shifted from being solubilized in diethyl ether to water.…
The instructor checked the apparatus and then put in 8 mL of anhydrous ether. The 4.5 mL of bromobenzene was added to the flask to make the Grignard reagent. The instructor added 12 mL of ether after the reaction changed colors clear to dark brown. The reaction was left to react for 30 minutes. During this time, 2.3 mL of methyl benzoate was obtained in a graduated cylinder and…
The modifications allowed for the reaction to be greener. The reaction created less waste (principle 1), atom economy was executed from the atoms being used in their entirety (principle 7), the use of no solvent created a safer reaction conditions of no requirement to extract the product (principle 8), and finally energy efficiency because the reaction was done at room temperature (principle 9). A weighted amount of 0.44grams of solid maleic acid anhydride was placed into a beaker along with 0.5 ml (about 10 drops) of (E,E)-2,4-hexadien-1-ol. The mixture was stirred with a metal spatula for 10 minutes under the fume hood until the complete liquefaction and resolidification occurred of a white solid.…
These different conditions included changing amounts of concentration in the substrates and enzymes, having the enzymes set up in different temperature environments and adding different amounts of the hydroxylamine inhibitor to the enzyme. During both weeks of lab observation we used a variety of substances, such as guaiacol; working as the color reagent, peroxidase; the enzyme, hydrogen peroxide; the substrate, distilled water and turnip extract in which was…
However, when the substrate concentration was increased, the intensity of color stopped increasing due to the enzymes being unable to to process at a faster rate. All of the alternate hypothesizes were supported; in the experiments, section one (with Figure 1) had an optimal temperature at approximately 24°C; section two (with Figure 2) had an optimal pH at approximately pH8; in section 3 (with Figure 3) the color continued to increase with the addition of more enzymes; and in section 4 (with Figure 4) the color continued to increase until it reached a maximum velocity with the addition of more substrates. One desired retrial for the experiment would be to test for more points after 20 drops of potato juice in Figure 3. Understanding the effects of how these properties alter the ability of the catecholase enzyme could allow for better insight into decreasing time needed for biochemical reactions, proper food storage, and the condition of…
The color of the clear water was expected to change into the color of the potassium permanganate dye, which was purple. Observation was shown to match with the expectation. When the dye crystal was put into the water at the beginning, it created the concentration gradient of water and the concentration gradient of the dye. The crystal itself had a higher concentration of potassium permanganate, and the water in the beaker had a lower concentration potassium permanganate. In other words, the water molecules in the beaker had a higher concentration of water, and the crystal had a lower…
The purpose of this lab is to observe the different colors produced by different compounds. My hypothesis is that each compound will produce a different color. For the procedure, we first took a wooden splint and placed it in distilled water. Then, we lit matches we received from Mr. Maloney, and turned on the gas which turned on the bunsen burner. We then took one compound from the front table.…
!!! Aniline: Structure and Formula Blue jeans - have you ever wondered about the dye where they get their color? One of the chemicals that is used to make the indigo dye used for our jeans is a substance called aniline. [{Image src='anilinepicture1.png' caption='Aniline is a Chemical Used to Make the Indigo Dye of Blue Jeans'}] Aniline is a flammable liquid chemical substance that has a pungent unpleasant odor and is slightly soluble in water. It can be colorless to brown, and it is oily to the touch.…
One important aspect of organic chemistry is the synthesis of new compounds. It is also important for chemists to understand how to perform certain techniques, such as extraction and distillation, to produce the new products, which are usually drugs and cures for illnesses. In this experiment, n-butyl bromide was produced. n-Butyl bromide is an alkyl halide, which are usually synthesized by an alcohol and an acid. In the case of n-butyl bromide, n-butyl alcohol was used along with sodium bromide and sulfuric acid.…
Amy Cuddy gave her speech called “ Your Body Language Shapes Who you Are,” she gave this prestigious speech on Ted Talk in June 2012. Cuddy discusses how “power posing,” such as sitting or standing in a specific posture of confidence, or even when you lack confidence, can affect the hormone called testosterone and cortisol which is a stress hormone in our bodies. Cuddy explains that having high levels of these hormones can cause a person to feel more confident, she described it as “fake it till you make it.” Its “fake it till you become it.” Furthermore, the overall construction of her speech is informative, since she used facts from supported research, and there was also some persuasion in her speech.…
It must be synthesized using several, sequential chemical reactions. Benzocaine is useful as a mild topical anesthetic that is the active ingredient in many anesthetic ointments such as Orajel for teething relief and Solarcaine, for sunburn relief. The four step synthesis of benzocaine (ethyl 4-aminobenzoate), 6, in this lab would typically result in overall benzocaine yield of 17.9% from the starting material p-toluidine, 1. Sharma and associates synthesized benzocaine beginning from vasicine with is found in the leaves of Adhatoda vasica. Specifically, nitro compounds were mixed with vascine in 120°C water for 24 hours and then purified by column chromatography. The final step involved the replacement of an amide with an amine.…