The silver nitrate combined with D-glucose, sodium citrate, and heat forms an aggregate. The citrate binds with the particle coating and dispels the repulsion between silver nitrate nanoparticles. The nanoparticles then form an aggregate-- a loose group of particles.
Batch C was resistant to aggregate formation. It did not include glucose, which reduces the silver nitrate and allows it to react with sodium citrate. The data from these batches was not within the wavelength window of silver nanoparticles